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4. Materials and corrosion

Cast iron

PT EN ES
Ferro fundido (cinzento) Cast iron / Gray iron Hierro fundido / Hierro gris

Iron-carbon alloy with carbon as graphite flakes. Inexpensive, easy to cast, good vibration damping. Used for non-corrosive water service at moderate temperatures (< 100 °C) and pressures.

Gotcha: plain cast iron is not suitable for thermal-oil pumps (temperature) or fire-pump casings (pressure rating + impact resistance). Specify ductile iron or cast steel for those.


Ductile iron (nodular cast iron)

PT EN ES
Ferro fundido nodular / Ferro dúctil Ductile iron / Nodular cast iron Hierro dúctil / Hierro fundido nodular

Cast iron with magnesium addition that turns the graphite from flakes to spheroids. Roughly 3× tensile strength and substantially higher impact resistance than gray cast iron. Common upgrade material for casings exposed to thermal cycling or shock loading.

ASTM A536 is the typical grade designation; common types include 60-40-18 and 65-45-12.


Cast steel

PT EN ES
Aço fundido Cast steel Acero fundido

Carbon or low-alloy steel cast into pump casings. Used where pressure, temperature, or impact requirements exceed ductile iron. Standard grade for API 610 process pumps (typically WCB or WCC per ASTM A216).


Stainless steel — austenitic (300 series)

PT EN ES
Aço inoxidável austenítico Austenitic stainless steel Acero inoxidable austenítico

Iron-chromium-nickel alloys, typically 18% Cr / 8% Ni base (304) or with molybdenum addition for chloride resistance (316). Non-magnetic, ductile, good general corrosion resistance.

Grade Composition Where used
304 / 1.4301 18% Cr, 8% Ni General mild service
304L / 1.4307 low-carbon variant Welded fabrications
316 / 1.4401 + 2-3% Mo Chloride-bearing fluids
316L / 1.4404 low-carbon Welded chloride service
321 / 1.4541 + Ti stabilizer High-temperature service (550-800 °C)

Gotcha: 304 is not chloride-resistant. Sea water, brackish water, and chlorinated cooling water need 316 minimum, often duplex.


Duplex and super-duplex stainless

PT EN ES
Aço inoxidável duplex / super-duplex Duplex / super-duplex stainless steel Acero inoxidable dúplex / súper dúplex

Stainless steels with mixed austenite-ferrite microstructure. Roughly 2× yield strength of 316 and superior chloride / pitting resistance.

Grade PREN range Where used
2205 / 1.4462 ~ 35 Standard duplex; sea-water at moderate temperature
2507 / 1.4410 ~ 42 Super-duplex; warm sea-water, brackish, sulfur-containing fluids

PREN = Pitting Resistance Equivalent Number = %Cr + 3.3 × %Mo + 16 × %N. PREN > 40 is the typical super-duplex threshold.


Hastelloy

PT EN ES
Hastelloy Hastelloy Hastelloy

Family of nickel-based alloys (Haynes International trademark) for severe corrosive service. Common grades:

Grade Resistant to
Hastelloy B-3 Concentrated hydrochloric acid
Hastelloy C-22 Oxidizing chlorides, mixed acids
Hastelloy C-276 Wet chlorine, hypochlorites, complex chlorinated solvents

Cost is typically 8-15× the cost of 316 stainless. Used only where cheaper materials cannot survive.


CD4MCu (cast duplex)

PT EN ES
CD4MCu CD4MCu CD4MCu

ASTM A890 cast duplex stainless. Common in pump impellers and casings for pulp & paper, mining, and chemical service. Roughly equivalent corrosion resistance to wrought 2205 with the casting-friendly composition.


Bronze (gunmetal, naval bronze)

PT EN ES
Bronze (canhão / náutico) Bronze (gunmetal / naval) Bronce (de cañón / naval)

Copper-tin alloys, sometimes with zinc, lead, or nickel additions. Used for sea-water pump impellers (B62 gunmetal), marine fittings, and applications where the material must be non-sparking.

Gotcha: bronze is dezincified by some chloride-bearing waters, especially soft acidic waters. For hot or acidic sea-water service, specify duplex or higher-grade alloys.


Elastomers (O-rings and gaskets)

PT EN ES
Elastômeros (anéis O-ring e juntas) Elastomers (O-rings and gaskets) Elastómeros (juntas tóricas y juntas)
Material Temperature range Resistant to Avoid
NBR (Buna-N) -30 to +100 °C Petroleum oils, water Polar solvents, ozone
EPDM -40 to +150 °C Hot water, steam, weak acids Petroleum oils, fuels
FKM (Viton) -20 to +200 °C Most chemicals, oils, fuels Hot amines, MEK, esters
FFKM (Kalrez) -20 to +325 °C Almost everything Cost (10-30× FKM)
PTFE -200 to +260 °C Almost everything Mechanical creep
Aflas -10 to +230 °C Amines, sour gas, acids Cost

Gotcha: “Viton” is a Chemours trademark for a specific FKM grade family. Generic FKM is the correct technical term. PT and ES catalogs use “Viton” loosely as a synonym for FKM, which can produce procurement mismatches between buyer and vendor.


See also